Simultaneous Immobilization of CO2 and H2S by Propargyl Amines under Mild Conditions: Efficient Synthesis of Thiazolidine-2-ones

Simultaneous Immobilization of CO2 and H2S by Propargyl Amines under Mild Conditions: Efficient Synthesis of Thiazolidine-2-ones

A series of thiazolidine-2-one derivatives were synthesized by a three-component reaction of carbon dioxide, hydrogen sulfide, and propargyl amines under mild conditions. The simultaneous incorporation of carbon dioxide and hydrogen sulfide into the same organic product was realized. Moreover, a rea...

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Veröffentlicht in:ACS sustainable chemistry & engineering 2022-01, Vol.10 (3), p.1214-1219
Hauptverfasser: Wu, Jiakai, He, Rongting, Cheng, Siliu, Han, Limin, Hong, Hailong, Zhu, Ning
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He, Rongting
Cheng, Siliu
Han, Limin
Hong, Hailong
Zhu, Ning
description A series of thiazolidine-2-one derivatives were synthesized by a three-component reaction of carbon dioxide, hydrogen sulfide, and propargyl amines under mild conditions. The simultaneous incorporation of carbon dioxide and hydrogen sulfide into the same organic product was realized. Moreover, a reaction mechanism was proposed based on the detailed NMR and FTIR study, which indicated that propargyl amine reacted with CO2 first to form carbamate, followed by O/S exchange with H2S to form thiocarbamate and the final cyclization of thiocarbamate to form thiazolidine-2-one.
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title Simultaneous Immobilization of CO2 and H2S by Propargyl Amines under Mild Conditions: Efficient Synthesis of Thiazolidine-2-ones
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