Chromophore Quench-Labeling: An Approach to Quantifying Catalyst Speciation As Demonstrated for (EBI)ZrMe2/B(C6F5)3‑Catalyzed Polymerization of 1‑Hexene

Chromophore-containing quench agents 2 and 3 enable quantitative active site counting and determination of the mass distribution of active catalyst polymeryls by refractive index (RI) and UV detected gel permeation chromatography (GPC) for the polymerization of 1-hexene catalyzed by (EBI)­ZrMe2/B­(C...

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Veröffentlicht in:ACS catalysis 2016-11, Vol.6 (11), p.7398-7408
Hauptverfasser: Nelsen, D. Luke, Anding, Bernie J, Sawicki, Julie L, Christianson, Matthew D, Arriola, Daniel J, Landis, Clark R
Format: Artikel
Sprache:eng ; jpn
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