Nickel-Catalyzed Csp2–Csp3 Cross-Coupling via C–O Bond Activation

A new and efficient nickel-catalyzed alkylation of CAr–O electrophiles with B-alkyl-9-BBNs is described. The transformation is characterized by its functional group tolerance and provides a practical and versatile access to various Csp2–Csp3 bonds through Csp2–O substitution, without the restriction...

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Veröffentlicht in:	ACS catalysis 2016-07, Vol.6 (7), p.4438-4442
Hauptverfasser:	Guo, Lin, Hsiao, Chien-Chi, Yue, Huifeng, Liu, Xiangqian, Rueping, Magnus
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Sprache:	eng ; jpn
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creator	Guo, Lin Hsiao, Chien-Chi Yue, Huifeng Liu, Xiangqian Rueping, Magnus
description	A new and efficient nickel-catalyzed alkylation of CAr–O electrophiles with B-alkyl-9-BBNs is described. The transformation is characterized by its functional group tolerance and provides a practical and versatile access to various Csp2–Csp3 bonds through Csp2–O substitution, without the restriction of β-hydride elimination. Moreover, the advantage of the newly developed method was demonstrated in a selective and sequential C–O bond activation process.
doi_str_mv	10.1021/acscatal.6b00801
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title	Nickel-Catalyzed Csp2–Csp3 Cross-Coupling via C–O Bond Activation
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