Unintuitive Inverse Dependence of the Apparent Turnover Frequency on Precatalyst Concentration: A Quantitative Explanation in the Case of Ziegler-Type Nanoparticle Catalysts Made from [(1,5-COD)Ir(μ‑O2C8H15)]2 and AlEt3

The Ziegler-type hydrogenation precatalyst dimer, [(1,5-COD)­Ir­(μ-O2C8H15)]2 (1,5-COD = 1,5-cyclooctadiene; O2C8H15 = 2-ethylhexanoate) plus added AlEt3 stabilizer has recently been shown to form AlEt3-stabilized, Ziegler-type Ir(0)∼4–15 nanoparticles initially, which then grow to larger Ziegler-ty...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	ACS catalysis 2015-06, Vol.5 (6), p.3342-3353
Hauptverfasser:	Crooks, Adam B, Yih, Kuang-Hway, Li, Long, Yang, Judith C, Özkar, Saim, Finke, Richard G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!