Cu Vacancy Induced Product Switching from Formate to CO for CO2 Reduction on Copper Sulfide

Cu is commonly modified with sulfur to obtain high selectivity for formate since S can promote the formation of the key *OCHO intermediate along the formate pathway. In the present work, we demonstrate that Cu-vacancies on copper sulfide can surprisingly switch the formate pathway to the CO pathway,...

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Veröffentlicht in:	ACS catalysis 2022-08, Vol.12 (15), p.9074-9082
Hauptverfasser:	Li, Simeng, Duan, Huan, Yu, Jun, Qiu, Chen, Yu, Rongxing, Chen, Yanpeng, Fang, Yueping, Cai, Xin, Yang, Shihe
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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