Unusual Role of P–P Bonds on Melt Dynamics and Topological Phases of the Equimolar Ge x P x Se100–2x Glass System

Equimolar Ge x P x Se100–2x ternary glasses have been synthesized over a wide composition range, 4% < x < 25%, and examined in Raman scattering, modulated DSC, and volumetric experiments. Modulated DSC experiments show the enthalpy of relaxation at T g to display a square-well-like reversibili...

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Veröffentlicht in:Journal of physical chemistry. C 2020-11, Vol.124 (45), p.25087-25106
Hauptverfasser: Welton, Aaron, Chbeir, Ralph, McDonald, Maxwell, Burger, Matthew, Almutairi, Badriah S, Chakravarty, Soumendu, Boolchand, Punit
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Sprache:eng
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