Revisiting the Solid–Liquid Phase Equilibrium of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O Systems

Revisiting the Solid–Liquid Phase Equilibrium of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O Systems

Solid–liquid phase equilibrium data of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O systems are of importance for the design of alkali metal element extraction processes from sulfate leaching solution of lepidolite. Considering the serious inconsistency of the reported solid phases, especiall...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of chemical and engineering data 2023-10, Vol.68 (10), p.2735-2741
Hauptverfasser: Fan, Yanfei, Zhuang, Ziyu, Gao, Dandan, Li, Dongdong, Zeng, Dewen
Format: Artikel
Sprache:eng
Schlagworte:
Solid-Solid Equilibria and Solid-Fluid Equilibria
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 2741
container_issue 10
container_start_page 2735
container_title Journal of chemical and engineering data
container_volume 68
creator Fan, Yanfei
Zhuang, Ziyu
Gao, Dandan
Li, Dongdong
Zeng, Dewen
description Solid–liquid phase equilibrium data of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O systems are of importance for the design of alkali metal element extraction processes from sulfate leaching solution of lepidolite. Considering the serious inconsistency of the reported solid phases, especially double salts and solid solutions, phase diagrams of the two systems were reinvestigated experimentally. The results on the Li2SO4 + Rb2SO4 + H2O system at 298.15 K show five solids, i.e., Rb2SO4, Rb2SO4·Li2SO4, Rb2SO4·3Li2SO4·2H2O, Rb2SO4·5Li2SO4·4H2O, and a solid solution with the end members Rb2SO4·5Li2SO4·4H2O and Li2SO4·H2O. For the Li2SO4 + Cs2SO4 + H2O system at 298.15 K, the results also show five solids, i.e., Cs2SO4, Cs2SO4·Li2SO4, Cs2SO4·3Li2SO4·2H2O, Cs2SO4·5Li2SO4·4H2O, and Li2SO4·H2O, while there is no solid solution phase with the end members Cs2SO4·5Li2SO4·4H2O and Li2SO4·H2O. Moreover, the single crystal structures of Rb2SO4·3Li2SO4·2H2O and Cs2SO4·3Li2SO4·2H2O were determined.
doi_str_mv 10.1021/acs.jced.3c00434
format Article
fullrecord <record><control><sourceid>acs</sourceid><recordid>TN_cdi_acs_journals_10_1021_acs_jced_3c00434</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>i23078915</sourcerecordid><originalsourceid>FETCH-LOGICAL-a192t-566e4ba2cb579e0635424e96213cfced377ae613c7e7632d2073a477e9f9fcc3</originalsourceid><addsrcrecordid>eNpNUE1LxDAUDKJgXb17zF1b8x1zlLLuCoXKdu8lTVM3pdviphW8-R_8h_4S41rQ05v3ZpjhDQDXGCUYEXynjU9aY-uEGoQYZScgwpygmGPKTkGEgiZWXNyfgwvvWxQ0kuAI9Bv75rwbXf8Cx52FxdC5-uvjM3Ovk6vh8057C5cBd646uGkPh-aoyxwpcgZv4KaawZrkUPf1H5P6f0zx7ke795fgrNGdt1fzXIDt43KbruMsXz2lD1mssSJjzIWwrNLEVFwqiwTljDCrBMHUNOFJKqW2IizSSkFJTZCkmklpVaMaY-gC3P7ahlbKdpgOfQgrMSp_qiqPx-BSzlXRb3rHWtk</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Revisiting the Solid–Liquid Phase Equilibrium of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O Systems</title><source>American Chemical Society Journals</source><creator>Fan, Yanfei ; Zhuang, Ziyu ; Gao, Dandan ; Li, Dongdong ; Zeng, Dewen</creator><creatorcontrib>Fan, Yanfei ; Zhuang, Ziyu ; Gao, Dandan ; Li, Dongdong ; Zeng, Dewen</creatorcontrib><description>Solid–liquid phase equilibrium data of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O systems are of importance for the design of alkali metal element extraction processes from sulfate leaching solution of lepidolite. Considering the serious inconsistency of the reported solid phases, especially double salts and solid solutions, phase diagrams of the two systems were reinvestigated experimentally. The results on the Li2SO4 + Rb2SO4 + H2O system at 298.15 K show five solids, i.e., Rb2SO4, Rb2SO4·Li2SO4, Rb2SO4·3Li2SO4·2H2O, Rb2SO4·5Li2SO4·4H2O, and a solid solution with the end members Rb2SO4·5Li2SO4·4H2O and Li2SO4·H2O. For the Li2SO4 + Cs2SO4 + H2O system at 298.15 K, the results also show five solids, i.e., Cs2SO4, Cs2SO4·Li2SO4, Cs2SO4·3Li2SO4·2H2O, Cs2SO4·5Li2SO4·4H2O, and Li2SO4·H2O, while there is no solid solution phase with the end members Cs2SO4·5Li2SO4·4H2O and Li2SO4·H2O. Moreover, the single crystal structures of Rb2SO4·3Li2SO4·2H2O and Cs2SO4·3Li2SO4·2H2O were determined.</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/acs.jced.3c00434</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Solid-Solid Equilibria and Solid-Fluid Equilibria</subject><ispartof>Journal of chemical and engineering data, 2023-10, Vol.68 (10), p.2735-2741</ispartof><rights>2023 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-3968-4767 ; 0000-0002-2206-8298 ; 0000-0003-0858-8606</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.jced.3c00434$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.jced.3c00434$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>315,782,786,27083,27931,27932,56745,56795</link.rule.ids></links><search><creatorcontrib>Fan, Yanfei</creatorcontrib><creatorcontrib>Zhuang, Ziyu</creatorcontrib><creatorcontrib>Gao, Dandan</creatorcontrib><creatorcontrib>Li, Dongdong</creatorcontrib><creatorcontrib>Zeng, Dewen</creatorcontrib><title>Revisiting the Solid–Liquid Phase Equilibrium of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O Systems</title><title>Journal of chemical and engineering data</title><addtitle>J. Chem. Eng. Data</addtitle><description>Solid–liquid phase equilibrium data of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O systems are of importance for the design of alkali metal element extraction processes from sulfate leaching solution of lepidolite. Considering the serious inconsistency of the reported solid phases, especially double salts and solid solutions, phase diagrams of the two systems were reinvestigated experimentally. The results on the Li2SO4 + Rb2SO4 + H2O system at 298.15 K show five solids, i.e., Rb2SO4, Rb2SO4·Li2SO4, Rb2SO4·3Li2SO4·2H2O, Rb2SO4·5Li2SO4·4H2O, and a solid solution with the end members Rb2SO4·5Li2SO4·4H2O and Li2SO4·H2O. For the Li2SO4 + Cs2SO4 + H2O system at 298.15 K, the results also show five solids, i.e., Cs2SO4, Cs2SO4·Li2SO4, Cs2SO4·3Li2SO4·2H2O, Cs2SO4·5Li2SO4·4H2O, and Li2SO4·H2O, while there is no solid solution phase with the end members Cs2SO4·5Li2SO4·4H2O and Li2SO4·H2O. Moreover, the single crystal structures of Rb2SO4·3Li2SO4·2H2O and Cs2SO4·3Li2SO4·2H2O were determined.</description><subject>Solid-Solid Equilibria and Solid-Fluid Equilibria</subject><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpNUE1LxDAUDKJgXb17zF1b8x1zlLLuCoXKdu8lTVM3pdviphW8-R_8h_4S41rQ05v3ZpjhDQDXGCUYEXynjU9aY-uEGoQYZScgwpygmGPKTkGEgiZWXNyfgwvvWxQ0kuAI9Bv75rwbXf8Cx52FxdC5-uvjM3Ovk6vh8057C5cBd646uGkPh-aoyxwpcgZv4KaawZrkUPf1H5P6f0zx7ke795fgrNGdt1fzXIDt43KbruMsXz2lD1mssSJjzIWwrNLEVFwqiwTljDCrBMHUNOFJKqW2IizSSkFJTZCkmklpVaMaY-gC3P7ahlbKdpgOfQgrMSp_qiqPx-BSzlXRb3rHWtk</recordid><startdate>20231012</startdate><enddate>20231012</enddate><creator>Fan, Yanfei</creator><creator>Zhuang, Ziyu</creator><creator>Gao, Dandan</creator><creator>Li, Dongdong</creator><creator>Zeng, Dewen</creator><general>American Chemical Society</general><scope/><orcidid>https://orcid.org/0000-0002-3968-4767</orcidid><orcidid>https://orcid.org/0000-0002-2206-8298</orcidid><orcidid>https://orcid.org/0000-0003-0858-8606</orcidid></search><sort><creationdate>20231012</creationdate><title>Revisiting the Solid–Liquid Phase Equilibrium of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O Systems</title><author>Fan, Yanfei ; Zhuang, Ziyu ; Gao, Dandan ; Li, Dongdong ; Zeng, Dewen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a192t-566e4ba2cb579e0635424e96213cfced377ae613c7e7632d2073a477e9f9fcc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Solid-Solid Equilibria and Solid-Fluid Equilibria</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fan, Yanfei</creatorcontrib><creatorcontrib>Zhuang, Ziyu</creatorcontrib><creatorcontrib>Gao, Dandan</creatorcontrib><creatorcontrib>Li, Dongdong</creatorcontrib><creatorcontrib>Zeng, Dewen</creatorcontrib><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fan, Yanfei</au><au>Zhuang, Ziyu</au><au>Gao, Dandan</au><au>Li, Dongdong</au><au>Zeng, Dewen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Revisiting the Solid–Liquid Phase Equilibrium of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O Systems</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>2023-10-12</date><risdate>2023</risdate><volume>68</volume><issue>10</issue><spage>2735</spage><epage>2741</epage><pages>2735-2741</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><abstract>Solid–liquid phase equilibrium data of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O systems are of importance for the design of alkali metal element extraction processes from sulfate leaching solution of lepidolite. Considering the serious inconsistency of the reported solid phases, especially double salts and solid solutions, phase diagrams of the two systems were reinvestigated experimentally. The results on the Li2SO4 + Rb2SO4 + H2O system at 298.15 K show five solids, i.e., Rb2SO4, Rb2SO4·Li2SO4, Rb2SO4·3Li2SO4·2H2O, Rb2SO4·5Li2SO4·4H2O, and a solid solution with the end members Rb2SO4·5Li2SO4·4H2O and Li2SO4·H2O. For the Li2SO4 + Cs2SO4 + H2O system at 298.15 K, the results also show five solids, i.e., Cs2SO4, Cs2SO4·Li2SO4, Cs2SO4·3Li2SO4·2H2O, Cs2SO4·5Li2SO4·4H2O, and Li2SO4·H2O, while there is no solid solution phase with the end members Cs2SO4·5Li2SO4·4H2O and Li2SO4·H2O. Moreover, the single crystal structures of Rb2SO4·3Li2SO4·2H2O and Cs2SO4·3Li2SO4·2H2O were determined.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.jced.3c00434</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-3968-4767</orcidid><orcidid>https://orcid.org/0000-0002-2206-8298</orcidid><orcidid>https://orcid.org/0000-0003-0858-8606</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0021-9568
ispartof Journal of chemical and engineering data, 2023-10, Vol.68 (10), p.2735-2741
issn 0021-9568
1520-5134
language eng
recordid cdi_acs_journals_10_1021_acs_jced_3c00434
source American Chemical Society Journals
subjects Solid-Solid Equilibria and Solid-Fluid Equilibria
title Revisiting the Solid–Liquid Phase Equilibrium of the Li2SO4 + Rb2SO4 + H2O and Li2SO4 + Cs2SO4 + H2O Systems
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-05T09%3A25%3A04IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Revisiting%20the%20Solid%E2%80%93Liquid%20Phase%20Equilibrium%20of%20the%20Li2SO4%20+%20Rb2SO4%20+%20H2O%20and%20Li2SO4%20+%20Cs2SO4%20+%20H2O%20Systems&rft.jtitle=Journal%20of%20chemical%20and%20engineering%20data&rft.au=Fan,%20Yanfei&rft.date=2023-10-12&rft.volume=68&rft.issue=10&rft.spage=2735&rft.epage=2741&rft.pages=2735-2741&rft.issn=0021-9568&rft.eissn=1520-5134&rft_id=info:doi/10.1021/acs.jced.3c00434&rft_dat=%3Cacs%3Ei23078915%3C/acs%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true