KMg(H2O)PO4: A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO4

KMg(H2O)PO4: A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO4

Discovery of new nonlinear optical (NLO) crystals, especially crystals that can produce coherent light in the deep-ultraviolet (DUV) region is essential for the development of diverse fields. Here, we successfully discovered and synthesized a new DUV transparent NLO crystal KMg­(H2O)­PO4 (KMP) using...

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Veröffentlicht in:Chemistry of materials 2019-11, Vol.31 (22), p.9540-9545
Hauptverfasser: Bai, Zhiyong, Hu, Chun-Li, Liu, Lehui, Zhang, Lizhen, Huang, Yisheng, Yuan, Feifei, Lin, Zhoubin
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container_issue 22
container_start_page 9540
container_title Chemistry of materials
container_volume 31
creator Bai, Zhiyong
Hu, Chun-Li
Liu, Lehui
Zhang, Lizhen
Huang, Yisheng
Yuan, Feifei
Lin, Zhoubin
description Discovery of new nonlinear optical (NLO) crystals, especially crystals that can produce coherent light in the deep-ultraviolet (DUV) region is essential for the development of diverse fields. Here, we successfully discovered and synthesized a new DUV transparent NLO crystal KMg­(H2O)­PO4 (KMP) using KTiOPO4 (KTP) as a template through substituting TiO6 by the MgO5(H2O) group. Its structure constructed by 2D [MgPO5]∞ infinite layers in which PO4 groups arrange orderly leads to KMP exhibiting a large second harmonic generation (SHG) efficiency (≈1.14 × KDP) which is similar to KBe2BO3F2 (1.2 × KDP). Moreover, the ultraviolet cut-off edge of KMP is blue-shifted to
doi_str_mv 10.1021/acs.chemmater.9b03950
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