A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals

A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals

A series of new noncentrosymmetric beryllium sulfates, A2BeS2O8 (A = NH4, K, Rb, Cs), were rationally designed and synthesized based on the parent borophosphates KMBP2O8 (M = Sr, Ba). Owing to the rigid three-dimensional frameworks, A2BeS2O8 (A = NH4, K, Rb, Cs) showed the high thermodynamic stabili...

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Veröffentlicht in:Chemistry of materials 2022-04, Vol.34 (8), p.3781-3788
Hauptverfasser: Sun, Yingshuang, Lin, Chensheng, Tian, Haotian, Zhou, Yuqiao, Chen, Jindong, Yang, Shunda, Ye, Ning, Luo, Min
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container_end_page 3788
container_issue 8
container_start_page 3781
container_title Chemistry of materials
container_volume 34
creator Sun, Yingshuang
Lin, Chensheng
Tian, Haotian
Zhou, Yuqiao
Chen, Jindong
Yang, Shunda
Ye, Ning
Luo, Min
description A series of new noncentrosymmetric beryllium sulfates, A2BeS2O8 (A = NH4, K, Rb, Cs), were rationally designed and synthesized based on the parent borophosphates KMBP2O8 (M = Sr, Ba). Owing to the rigid three-dimensional frameworks, A2BeS2O8 (A = NH4, K, Rb, Cs) showed the high thermodynamic stabilities. Among them, A2BeS2O8 (A = K, Rb, Cs) exhibited the highest thermodynamic stabilities among all the reported nonlinear (NLO) sulfates. In addition, benefiting from the flexible Be–O bonds within [BeO4], A2BeS2O8 (A = NH4, K, Rb, Cs) exhibited the enhanced second harmonic generation (SHG) responses, which were about 3 to 5 times that of parent borophosphates. Furthermore, they possessed a moderate birefringence of 0.013–0.024 and could be transparent down to the deep ultraviolet (DUV) region below 200 nm. This work indicated that the basic building blocks in borophosphates and beryllium sulfates were potentially interchangeable, which provided the possibility for a further study of new NLO crystals.
doi_str_mv 10.1021/acs.chemmater.2c00225
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Owing to the rigid three-dimensional frameworks, A2BeS2O8 (A = NH4, K, Rb, Cs) showed the high thermodynamic stabilities. Among them, A2BeS2O8 (A = K, Rb, Cs) exhibited the highest thermodynamic stabilities among all the reported nonlinear (NLO) sulfates. In addition, benefiting from the flexible Be–O bonds within [BeO4], A2BeS2O8 (A = NH4, K, Rb, Cs) exhibited the enhanced second harmonic generation (SHG) responses, which were about 3 to 5 times that of parent borophosphates. Furthermore, they possessed a moderate birefringence of 0.013–0.024 and could be transparent down to the deep ultraviolet (DUV) region below 200 nm. 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