Halonitrides Zn2NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials
Continuously, nitrides are mainly regarded as semiconductors or thermal conductivity materials and applied in photonic devices. In this work, we proposed that nitrides may also be a new system for mid-infrared (mid-IR) nonlinear optical (NLO) materials. Meanwhile, we first report the halonitrides Zn...
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| Veröffentlicht in: | Chemistry of materials 2021-02, Vol.33 (4), p.1462-1470 |
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| container_title | Chemistry of materials |
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| creator | Zhao, Xin Lin, Chensheng Chen, Jindong Luo, Min Xu, Feng Yang, Shunda Shi, Shuangshuang Li, Bingxuan Ye, Ning |
| description | Continuously, nitrides are mainly regarded as semiconductors or thermal conductivity materials and applied in photonic devices. In this work, we proposed that nitrides may also be a new system for mid-infrared (mid-IR) nonlinear optical (NLO) materials. Meanwhile, we first report the halonitrides Zn2NX (X = Cl, Br) as mid-IR NLO crystals, which were synthesized by a solid–liquid reaction. Both compounds show excellent optical properties including large band gaps (3.21 and 3.28 eV), strong second-harmonic generation responses (0.9 and 0.8 × AGS), a wide IR transparent range (0.37–8.0 μm for Zn2NBr) and moderate birefringences (Δn = 0.060 and 0.063). Also, the powder laser damage threshold (LDT) measurements revealed that they had high LDTs (20.7 and 25.9 × AGS). This study suggests that not only nitrides may be potential and outstanding mid-IR NLO candidates but also the combination of different anions into one structure will be a feasible strategy to discover high-performance NLO materials. |
| doi_str_mv | 10.1021/acs.chemmater.0c04772 |
| format | Article |
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In this work, we proposed that nitrides may also be a new system for mid-infrared (mid-IR) nonlinear optical (NLO) materials. Meanwhile, we first report the halonitrides Zn2NX (X = Cl, Br) as mid-IR NLO crystals, which were synthesized by a solid–liquid reaction. Both compounds show excellent optical properties including large band gaps (3.21 and 3.28 eV), strong second-harmonic generation responses (0.9 and 0.8 × AGS), a wide IR transparent range (0.37–8.0 μm for Zn2NBr) and moderate birefringences (Δn = 0.060 and 0.063). Also, the powder laser damage threshold (LDT) measurements revealed that they had high LDTs (20.7 and 25.9 × AGS). 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| title | Halonitrides Zn2NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials |
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