Screening Ferroelastic Transitions in Switchable Cyano-Bridged Perovskites: [CH3C(NH2)2]2[KM(CN)6], M = Cr3+, Fe3+, Co3+. Crystal Structure Characterization, Dielectric Properties, 1H NMR, and Quasielastic Neutron Scattering Studies
Here we report the dynamics of organic cations as guest molecules in the novel perovskite host framework. The novel switchable crystals from the coordination family [CH3C(NH2)2]2[KB″(CN)6] were constructed by employing acetamidinium cations (ACE = [CH3C(NH2)2]) as A-site and B″: Cr3+, Fe3+, Co3+...
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Veröffentlicht in: | Crystal growth & design 2019-08, Vol.19 (8), p.4526-4537 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng ; jpn |
Online-Zugang: | Volltext |
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