Screening Ferroelastic Transitions in Switchable Cyano-Bridged Perovskites: [CH3C(NH2)2]2­[KM(CN)6], M = Cr3+, Fe3+, Co3+. Crystal Structure Characterization, Dielectric Properties, 1H NMR, and Quasielastic Neutron Scattering Studies

Here we report the dynamics of organic cations as guest molecules in the novel perovskite host framework. The novel switchable crystals from the coordination family [CH3C­(NH2)2]2­[KB″(CN)6] were constructed by employing acetamidinium cations (ACE = [CH3C­(NH2)2]) as A-site and B″: Cr3+, Fe3+, Co3+...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Crystal growth & design 2019-08, Vol.19 (8), p.4526-4537
Hauptverfasser: Rok, Magdalena, Bator, Grażyna, Zarychta, Bartosz, Dziuk, Błażej, Skałecki, Damian K, Medycki, Wojciech, Zamponi, Michaela
Format: Artikel
Sprache:eng ; jpn
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!