Defect and Surface Area Control in Hydrothermally Synthesized LiMn0.8Fe0.2PO4 Using a Phosphate Based Structure Directing Agent

Defect and Surface Area Control in Hydrothermally Synthesized LiMn0.8Fe0.2PO4 Using a Phosphate Based Structure Directing Agent

As confirmed by ion coupled plasma-optical emission spectroscopy and powder X-ray diffraction, stoichiometrically pure samples of olivine type LiFe0.2Mn0.8PO4 in the presence of a phosphoric acid ester based structure directing agent have been prepared. A Rietveld analysis of X-ray and n0 diffractio...

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Veröffentlicht in:Crystal growth & design 2015-09, Vol.15 (9), p.4213-4218
Hauptverfasser: Schoiber, Jürgen, Tippelt, Gerold, Redhammer, Günther J, Yada, Chihiro, Dolotko, Oleksandr, Berger, Raphael J. F, Hüsing, Nicola
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container_end_page 4218
container_issue 9
container_start_page 4213
container_title Crystal growth & design
container_volume 15
creator Schoiber, Jürgen
Tippelt, Gerold
Redhammer, Günther J
Yada, Chihiro
Dolotko, Oleksandr
Berger, Raphael J. F
Hüsing, Nicola
description As confirmed by ion coupled plasma-optical emission spectroscopy and powder X-ray diffraction, stoichiometrically pure samples of olivine type LiFe0.2Mn0.8PO4 in the presence of a phosphoric acid ester based structure directing agent have been prepared. A Rietveld analysis of X-ray and n0 diffraction data suggests that the solids are largely free of defect occupation of Fe at the lithium sites. This is confirmed by 57Fe-Mößbauer spectroscopic investigations. The use of the structure directing surfactant results in significantly higher specific surface areas (SSA) and smaller particle sizes as compared to samples prepared without using a surfactant.
doi_str_mv 10.1021/acs.cgd.5b00324
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title Defect and Surface Area Control in Hydrothermally Synthesized LiMn0.8Fe0.2PO4 Using a Phosphate Based Structure Directing Agent
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