Structural Design of Mn-Metal–Organic Frameworks toward Highly Efficient Solvent-Free Cycloaddition of CO2

Structural Design of Mn-Metal–Organic Frameworks toward Highly Efficient Solvent-Free Cycloaddition of CO2

Three new manganese-based metal–organic frameworks (Mn-MOFs), [Mn­(L)­(H2O)]­·2DMA (1), [Mn2(L)2(H2O)3]­·2DMA (2), and [Mn2(L)2(DMF)2­(H2O)]­·3DMF (3), have been synthesized with the ligand H2L (N-phenyl-N′-phenylbicyclo­[2.2.2]­oct-7-ene-2,3,5,6-tetracarboxdiimide dicarboxylic acid). The secondary...

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Veröffentlicht in:Crystal growth & design 2021-07, Vol.21 (7), p.3728-3735
Hauptverfasser: Lin, Haonan, Deng, Cheng-Hua, Qiu, Xiaohang, Liu, Xiao, Ma, Jian-Gong, Cheng, Peng
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container_end_page 3735
container_issue 7
container_start_page 3728
container_title Crystal growth & design
container_volume 21
creator Lin, Haonan
Deng, Cheng-Hua
Qiu, Xiaohang
Liu, Xiao
Ma, Jian-Gong
Cheng, Peng
description Three new manganese-based metal–organic frameworks (Mn-MOFs), [Mn­(L)­(H2O)]­·2DMA (1), [Mn2(L)2(H2O)3]­·2DMA (2), and [Mn2(L)2(DMF)2­(H2O)]­·3DMF (3), have been synthesized with the ligand H2L (N-phenyl-N′-phenylbicyclo­[2.2.2]­oct-7-ene-2,3,5,6-tetracarboxdiimide dicarboxylic acid). The secondary building units (SBUs) of the Mn-MOFs are controlled by changing the anions of the manganese salts, and the structures are modified from two-fold interpenetrating to non-interpenetrating by adjusting the mixed solvent systems. Along with the structural modification of the Mn-MOFs, we optimized their catalytic activities for the reaction of CO2 and epoxides toward cyclic carbonates. Both the activity and reusability of the Mn-MOFs are successfully improved in the solvent-free cycloaddition of CO2 with various epoxides under the mild conditions of atmospheric pressure and 70 °C.
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title Structural Design of Mn-Metal–Organic Frameworks toward Highly Efficient Solvent-Free Cycloaddition of CO2
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