A Definitive Example of a Geometric “Entatic State” Effect:  Electron-Transfer Kinetics for a Copper(II/I) Complex Involving A Quinquedentate Macrocyclic Trithiaether−Bipyridine Li... von Chaka, Gezahegn, Sonnenberg, Jason L, Schlegel, H. Bernhard, Heeg, Mary Jane, Jaeger, Gregory, Nelson, Timothy J, Ochrymowycz, L. A, Rorabacher, D. B

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Influence of Coordination Geometry upon Copper(II/I) Redox Potentials. Physical Parameters for Twelve Copper Tripodal Ligand Complexes von Ambundo, Edna A, Deydier, Marie-Veronique, Grall, Andrew J, Aguera-Vega, Natalia, Dressel, Luke T, Cooper, Thomas H, Heeg, Mary Jane, Ochrymowycz, L. A, Rorabacher, D. B

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Physical Parameters and Electron-Transfer Kinetics of the Copper(II/I) Complex with the Macrocyclic Sexadentate Ligand [18]aneS6 von Chaka, Gezahegn, Ochrymowycz, L. A, Rorabacher, D. B

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Direct Evidence for a Geometrically Constrained “Entatic State” Effect on Copper(II/I) Electron-Transfer Kinetics As Manifested in Metastable Intermediates von Yu, Qiuyue, Salhi, Cynthia A, Ambundo, Edna A, Heeg, Mary Jane, Ochrymowycz, L. A, Rorabacher, D. B

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Effect of Constrained Donor Atom Orientations on the Stabilities, Complexation Kinetics, Redox Potentials, and Structures of Macrocyclic Polythiaether Complexes. Copper(II) Complex... von Kakos, Safaa H, Dressel, Luke T, Bushendorf, Jeffery D, Kotarba, Casimir P, Wijetunge, Prabodha, Kulatilleke, Chandrika P, McGillivary, Michael P, Chaka, Gezahegn, Heeg, Mary Jane, Ochrymowycz, L. A, Rorabacher, D. B

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Electron-Transfer Kinetics of Copper(II/I) Tripodal Ligand Complexes von Ambundo, Edna A., Yu, Qiuyue, Ochrymowycz, L. A., Rorabacher, D. B.

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Formation and Dissociation Kinetics and Crystal Structures of Nickel(II)−Macrocyclic Tetrathiaether Complexes in Acetonitrile. Comparison to Nickel(II)−Macrocyclic Tetramines von Kulatilleke, Chandrika P, Goldie, Scott N, Heeg, Mary Jane, Ochrymowycz, L. A, Rorabacher, D. B

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Kinetics and Mechanism of Copper(II) Complex Formation with Tripodal Aminopolythiaether and Aminopolypyridyl Ligands in Aqueous Solution von Ambundo, Edna A, Deydier, Marie-Veronique, Ochrymowycz, L. A, Rorabacher, D. B

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A Structural Strategy for Generating Rapid Electron-Transfer Kinetics in Copper(II/I) Systems von Krylova, Ksenia, Kulatilleke, Chandrika P, Heeg, Mary Jane, Salhi, Cynthia A, Ochrymowycz, L. A, Rorabacher, D. B

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Comparison of the influence of saturated nitrogen and sulfur donor atoms on the properties of copper(II/I)-macrocyclic polyamino polythiaether ligand complexes: redox potentials an... von Bernardo, M. Margarida, Heeg, Mary Jane, Schroeder, Ronald R, Ochrymowycz, L. A, Rorabacher, D. B

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Cyclic Voltammetric Evaluation of Rate Constants for Conformational Transitions Accompanying Electron Transfer. Effect of Varying Structural Constraints in Copper(II/I) Complexes w... von Villeneuve, Nicole M, Schroeder, Ronald R, Ochrymowycz, L. A, Rorabacher, D. B

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Effect of conformational constraints on gated electron-transfer kinetics. 3. Copper(II/I) complexes with cis- and trans-cyclopentanediyl-1,4,8,11-tetrathiacyclotetradecane von Wijetunge, P, Kulatilleke, C P, Dressel, L T, Heeg, M J, Ochrymowycz, L A, Rorabacher, D B

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Effect of Conformational Constraints on Gated Electron Transfer Kinetics. 2. Copper(II/I) Complexes with Phenyl-Substituted [14]aneS(4) Ligands in Acetonitrile(1) von Dunn, Brian C., Ochrymowycz, L. A., Rorabacher, D. B.

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Gated electron-transfer behavior in copper(II/I) systems. Comparison of the kinetics for homogeneous cross reactions, NMR self-exchange relaxation, and electrochemical data for a c... von Meagher, Nancy E., Juntunen, Kerri L., Salhi, Cynthia A., Ochrymowycz, L. A., Rorabacher, D. B.

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Unusually High Selectivity of Polythiaethers for Copper(II) over Nickel(II) von Kulatilleke, Chandrika P, Goldie, Scott N, Ochrymowycz, L. A, Rorabacher, D. B

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Electron-Transfer Kinetics of Tris(2-(methylthioethyl))aminecopper(II/I). A Tripodal Ligand Complex Exhibiting Virtual C3v Symmetry von AMBUNDO, Edna A., OCHRYMOWYCZ, L. A., RORABACHER, D. B.

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Electron-Transfer Kinetics of the Copper(II/I) Complex with 1,4,8,11-Tetrathiacyclotetradecane in Acetonitrile von Dunn, Brian C, Ochrymowycz, L. A, Rorabacher, D. B

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Ring Size, Substituent, and Anion Effects on the Kinetic and Equilibrium Properties of Copper(II) Complexes with Water-Soluble Macrocyclic Tetrathia Ethers von Krylova, Ksenia, Jackson, Kimberly D, Vroman, Jeffrey A, Grall, Andrew J, Snow, Michael R, Ochrymowycz, L. A, Rorabacher, D. B

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Structure-reactivity relationships in copper(II)/copper(I) electron-transfer kinetics: evaluation of self-exchange rate constants for copper polythia ether complexes von Martin, Michael J, Endicott, John F, Ochrymowycz, L. A, Rorabacher, D. B

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Electron-Transfer Kinetics and Thermodynamic Characterization of Copper(II/I) Complexes with Acyclic Tetrathiaethers in Aqueous Solution von Dunn, Brian C, Wijetunge, Prabodha, Vyvyan, James R, Howard, Turner A, Grall, Andrew J, Ochrymowycz, L. A, Rorabacher, D. B

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