Dramatic Effect of Carboxylic Acid on the Electronic Structure of the Active Species in Fe(PDP)-Catalyzed Asymmetric Epoxidation von Zima, Alexandra M, Lyakin, Oleg Y, Ottenbacher, Roman V, Bryliakov, Konstantin P, Talsi, Evgenii P

Volltext

EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation von Lyakin, Oleg Y, Bryliakov, Konstantin P, Britovsek, George J. P, Talsi, Evgenii P

Volltext

Highly efficient asymmetric aerobic oxidative coupling of 2-naphthols in the presence of bioinspired iron aminopyridine complexes von Tkachenko, Nikolay V., Lyakin, Oleg Y., Samsonenko, Denis G., Talsi, Evgenii P., Bryliakov, Konstantin P.

Volltext

Effect of Brønsted Acid on the Reactivity and Selectivity of the Oxoiron(V) Intermediates in C-H and C=C Oxidation Reactions von Zima, Alexandra M., Lyakin, Oleg Y., Bryliakova, Anna A., Babushkin, Dmitrii E., Bryliakov, Konstantin P., Talsi, Evgenii P.

Volltext

In Situ EPR Monitoring of Chromium Species Formed during Cr−Pyrrolyl Ethylene Trimerization Catalyst Formation von Skobelev, Igor Y, Panchenko, Valentina N, Lyakin, Oleg Y, Bryliakov, Konstantin P, Zakharov, Vladimir A, Talsi, Evgenii P

Volltext

Asymmetric Epoxidations with H2O2 on Fe and Mn Aminopyridine Catalysts: Probing the Nature of Active Species by Combined Electron Paramagnetic Resonance and Enantioselectivity Stud... von Lyakin, Oleg Y, Ottenbacher, Roman V, Bryliakov, Konstantin P, Talsi, Evgenii P

Volltext

Low‐Spin and High‐Spin Perferryl Intermediates in Non‐Heme Iron Catalyzed Oxidations of Aliphatic C−H Groups von Zima, Alexandra M., Lyakin, Oleg Y., Bryliakov, Konstantin P., Talsi, Evgenii P.

Volltext

Ni‐ and Pd‐based homogeneous catalyst systems for direct oxygenation of C(sp3)‐H groups von Lyakin, Oleg Y., Bushmin, Dmitry S., Talsi, Evgenii P., Bryliakov, Konstantin P.

Volltext

Diverting Ni‐Catalyzed Direct Benzylic C−H Hydroxylation towards Trifluoroethoxylation von Bushmin, Dmitry S., Samsonenko, Denis G., Talsi, Evgenii P., Lyakin, Oleg Y., Bryliakov, Konstantin P.

Volltext

Iron-Catalyzed Enantioselective Epoxidations with Various Oxidants: Evidence for Different Active Species and Epoxidation Mechanisms von Zima, Alexandra M, Lyakin, Oleg Y, Ottenbacher, Roman V, Bryliakov, Konstantin P, Talsi, Evgenii P

Volltext

Direct Evaluation of the Reactivity of Nonheme Iron(V)–Oxo Intermediates toward Arenes von Lyakin, Oleg Y, Zima, Alexandra M, Tkachenko, Nikolay V, Bryliakov, Konstantin P, Talsi, Evgenii P

Volltext

High‐Spin and Low‐Spin Perferryl Intermediates in Fe(PDP)‐Catalyzed Epoxidations von Zima, Alexandra M., Lyakin, Oleg Y., Bryliakov, Konstantin P., Talsi, Evgenii P.

Volltext

Reactivity vs. Selectivity of Biomimetic Catalyst Systems of the Fe(PDP) Family through the Nature and Spin State of the Active Iron‐Oxygen Species von Zima, Alexandra M., Lyakin, Oleg Y., Bryliakova, Anna A., Babushkin, Dmitrii E., Bryliakov, Konstantin P., Talsi, Evgenii P.

Volltext

Direct reactivity studies of non-heme iron-oxo intermediates toward alkane oxidation von Zima, Alexandra M., Lyakin, Oleg Y., Bryliakov, Konstantin P., Talsi, Evgenii P.

Volltext

High‐Spin and Low‐Spin State Perferryl Intermediates: Reactivity‐Selectivity Correlation in Fe(PDP) Catalyzed Oxidation of (+)‐Sclareolide von Zima, Alexandra M., Babushkin, Dmitrii E., Lyakin, Oleg Y., Bryliakov, Konstantin P., Talsi, Evgenii P.

Volltext

Remarkably fast oxidation of alkanes by hydrogen peroxide catalyzed by a tetracopper(II) triethanolaminate complex: Promoting effects of acid co-catalysts and water, kinetic and me... von Kirillova, Marina V., Kozlov, Yuriy N., Shul’pina, Lidia S., Lyakin, Oleg Y., Kirillov, Alexander M., Talsi, Evgenii P., Pombeiro, Armando J.L., Shul’pin, Georgiy B.

Volltext

Highly Efficient Aromatic C−H Oxidation with H2O2 in the Presence of Iron Complexes of the PDP Family von Tkachenko, Nikolay V., Ottenbacher, Roman V., Lyakin, Oleg Y., Zima, Alexandra M., Samsonenko, Denis G., Talsi, Evgenii P., Bryliakov, Konstantin P.

Volltext

Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts von Soshnikov, Igor E, Semikolenova, Nina V, Bushmelev, Alexey N, Bryliakov, Konstantin P, Lyakin, Oleg Y, Redshaw, Carl, Zakharov, Vladimir A, Talsi, Evgenii P

Volltext

Non-heme oxoiron(V) intermediates in chemo-, regio- and stereoselective oxidation of organic substrates von Lyakin, Oleg Y., Bryliakov, Konstantin P., Talsi, Evgenii P.

Volltext

EPR Spectroscopic Detection of the Elusive Fe V ═O Intermediates in Selective Catalytic Oxofunctionalizations of Hydrocarbons Mediated by Biomimetic Ferric Complexes von Lyakin, Oleg Y., Zima, Alexandra M., Samsonenko, Denis G., Bryliakov, Konstantin P., Talsi, Evgenii P.

Volltext