The modern interpretation of the Wittig reaction mechanism von Byrne, Peter A, Gilheany, Declan G

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First ever observation of the intermediate of phosphonium salt and ylide hydrolysis: P-hydroxytetraorganophosphorane von Byrne, Peter A, Ortin, Yannick, Gilheany, Declan G

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Asymmetric Grignard Synthesis of Tertiary Alcohols through Rational Ligand Design von Bieszczad, Bartosz, Gilheany, Declan G.

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Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride von Rajendran, Kamalraj V, Gilheany, Declan G

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Harnessing the Power of the Asymmetric Grignard Synthesis of Tertiary Alcohols: Ligand Development and Improved Scope Exemplified by One-Step Gossonorol Synthesis von Kavanagh, Saranna E, Gilheany, Declan G

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Chromium− and Manganese−salen Promoted Epoxidation of Alkenes von McGarrigle, Eoghan M, Gilheany, Declan G

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The Mechanism of Phosphonium Ylide Alcoholysis and Hydrolysis: Concerted Addition of the O−H Bond Across the P=C Bond von Byrne, Peter A., Gilheany, Declan G.

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Syntheses, Structures and Dynamics of 9‐(Ferrocenylmethyl)anthracene and Related Molecular Gears: Phosphorus to the Rescue von Nikitin, Kirill, Ortin, Yannick, Müller‐Bunz, Helge, Gilheany, Declan G., McGlinchey, Michael J.

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Synthesis of P-Stereogenic Phosphorus Compounds. Asymmetric Oxidation of Phosphines under Appel Conditions von Bergin, Enda, O'Connor, Cormac T, Robinson, Shane B, McGarrigle, Eoghan M, O'Mahony, Colm P, Gilheany, Declan G

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Lithium Borohydride for Achiral and ­Stereospecific Reductive Boronation at Phosphorus: Lack of Electronic Effects on Stereoselective Formation of Alkoxyphosphonium Salts von Al Sulaimi, Sulaiman S., Rajendran, Kamalraj V., Gilheany, Declan G.

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P-Stereogenic Phosphorus Compounds: Effect of Aryl Substituents on the Oxidation of Arylmethylphenylphosphanes under Asymmetric Appel Conditions von Rajendran, Kamalraj V., Kennedy, Lorna, Gilheany, Declan G.

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Unexpected rapid P -stereomutation of phosphine oxides catalysed by chlorophosphonium salts von Al-Sulaimi, Sulaiman, Rajendran, Kamalraj, Nikitin, Kirill, Gilheany, Declan G.

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A U-Turn in the Asymmetric Appel Reaction: Stereospecific Reduction of Diastereomerically Enriched Alkoxyphosphonium Salts Allows the Asymmetric Synthesis of P-Stereogenic Phosphan... von Rajendran, Kamalraj V., Kudavalli, Jaya S., Dunne, Katherine S., Gilheany, Declan G.

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Wittig Olefination Using Phosphonium Ion-Pair Reagents Incorporating an Endogenous Base von Vetter, Anna C, Gilheany, Declan G, Nikitin, Kirill

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Long sought synthesis of quaternary phosphonium salts from phosphine oxides: inverse reactivity approach von Vetter, Anna C, Nikitin, Kirill, Gilheany, Declan G

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Taming a Functional Group: Creating Air-Stable, Chiral Primary Phosphanes von Hiney, Rachel M., Higham, Lee J., Müller-Bunz, Helge, Gilheany, Declan G.

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Highly stereoselective construction of the C2 stereocentre of α-tocopherol (vitamin E) by asymmetric addition of Grignard reagents to ketones von Bieszczad, Bartosz, Gilheany, Declan G

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Degenerate Nucleophilic Substitution in Phosphonium Salts von Jennings, Elizabeth V, Nikitin, Kirill, Ortin, Yannick, Gilheany, Declan G

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Very short highly enantioselective Grignard synthesis of 2,2-disubstituted tetrahydrofurans and tetrahydropyrans von Monasterolo, Claudio, Müller-Bunz, Helge, Gilheany, Declan G

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Unequivocal Experimental Evidence for a Unified Lithium Salt-Free Wittig Reaction Mechanism for All Phosphonium Ylide Types: Reactions with β-Heteroatom-Substituted Aldehydes Are C... von Byrne, Peter A, Gilheany, Declan G

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