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Interpretazione di Archiloco: fr. 2D. = 7L.-B
Veröffentlicht in Rivista di Filologia e di Istruzione Classica
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Enantioselective 6-endo bromoaminocyclization of 2,4-dienyl N-tosylcarbamates catalyzed by a chiral phosphine oxide-Sc(OTf)3 complex. A dramatic additive effectElectronic supplementary information (ESI) available: Experimental, characterization data, X-ray structures of compounds 7a, 7h, 7i, 7l, 7m, 9a, 10a12a, 13a, and NMR spectra. CCDC 1038311-1038318 and 1038321. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ob00001g
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Design, synthesis and biological activity evaluation of regioisomeric spiro-(indoline-isoxazolidines) in the inhibition of TNF-α-induced ICAM-1 expression on human endothelial cellsElectronic supplementary information (ESI) available: 1H NMR and 13C NMR spectra of the novel bioactive final compounds 7k, 7l, 9k, 9l, 9n, 9o, 9p, 9c, 9e, and 9h. HPLC profiles for the purity check of the novel bioactive final compounds 7k, 7l, 9a, 9c, 9h-9q and 9s and selected known compounds 8b, 8c, 8g, 8h, 8j, 10b
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Rhodium-catalyzed enantioselective cyclopropanation of electron-deficient alkenesElectronic supplementary information (ESI) available: (1) Experimental data for the reported reactions and a CIF file for the X-ray crystallographic data for 7l, and 15, (2) completed ref. 20, (3) Fig. SI-3 including calculated structures, important geometry parameters (in ) and relative energies of the epoxidation of (a) acrylate, (b) acrylamide and methyl vinyl ketone, and (4) Cartesian coordinates all reported re
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