Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy von Reijerse, Edward J, Pham, Cindy C, Pelmenschikov, Vladimir, Gilbert-Wilson, Ryan, Adamska-Venkatesh, Agnieszka, Siebel, Judith F, Gee, Leland B, Yoda, Yoshitaka, Tamasaku, Kenji, Lubitz, Wolfgang, Rauchfuss, Thomas B, Cramer, Stephen P

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Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory von Pelmenschikov, Vladimir, Birrell, James A, Pham, Cindy C, Mishra, Nakul, Wang, Hongxin, Sommer, Constanze, Reijerse, Edward, Richers, Casseday P, Tamasaku, Kenji, Yoda, Yoshitaka, Rauchfuss, Thomas B, Lubitz, Wolfgang, Cramer, Stephen P

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X-Ray Spectroscopy with Synchrotron Radiation: Fundamentals and Applications von Cramer, Stephen P

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High-yield expression of heterologous [FeFe] hydrogenases in Escherichia coli von Kuchenreuther, Jon M, Grady-Smith, Celestine S, Bingham, Alyssa S, George, Simon J, Cramer, Stephen P, Swartz, James R

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The HydG Enzyme Generates an Fe(CO)2(CN) Synthon in Assembly of the FeFe Hydrogenase H-Cluster von Kuchenreuther, Jon M., Myers, William K., Suess, Daniel L. M., Stich, Troy A., Pelmenschikov, Vladimir, Shiigi, Stacey A., Cramer, Stephen P., Swartz, James R., Britt, R. David, George, Simon J.

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Terminal Hydride Species in [FeFe]‐Hydrogenases Are Vibrationally Coupled to the Active Site Environment von Pham, Cindy C., Mulder, David W., Pelmenschikov, Vladimir, King, Paul W., Ratzloff, Michael W., Wang, Hongxin, Mishra, Nakul, Alp, Esen E., Zhao, Jiyong, Hu, Michael Y., Tamasaku, Kenji, Yoda, Yoshitaka, Cramer, Stephen P.

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Temperature-dependent iron motion in extremophile rubredoxins – no need for ‘corresponding states’ von Jenney, Francis E., Wang, Hongxin, George, Simon J., Xiong, Jin, Guo, Yisong, Gee, Leland B., Marizcurrena, Juan José, Castro-Sowinski, Susana, Staskiewicz, Anna, Yoda, Yoshitaka, Hu, Michael Y., Tamasaku, Kenji, Nagasawa, Nobumoto, Li, Lei, Matsuura, Hiroaki, Doukov, Tzanko, Cramer, Stephen P.

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Cysteine as a ligand platform in the biosynthesis of the FeFe hydrogenase H cluster von Suess, Daniel L. M., Bürstel, Ingmar, De La Paz, Liliana, Kuchenreuther, Jon M., Pham, Cindy C., Cramer, Stephen P., Swartz, James R., Britt, R. David

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Enzymatic and spectroscopic properties of a thermostable [NiFe]‑hydrogenase performing H2-driven NAD+-reduction in the presence of O2 von Preissler, Janina, Wahlefeld, Stefan, Lorent, Christian, Teutloff, Christian, Horch, Marius, Lauterbach, Lars, Cramer, Stephen P., Zebger, Ingo, Lenz, Oliver

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Nuclear Resonance Vibrational Spectroscopy: A Modern Tool to Pinpoint Site-Specific Cooperative Processes von Wang, Hongxin, Braun, Artur, Cramer, Stephen P., Gee, Leland B., Yoda, Yoshitaka

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Sterically Stabilized Terminal Hydride of a Diiron Dithiolate von Carlson, Michaela R, Gray, Danielle L, Richers, Casseday P, Wang, Wenguang, Zhao, Pei-Hua, Rauchfuss, Thomas B, Pelmenschikov, Vladimir, Pham, Cindy C, Gee, Leland B, Wang, Hongxin, Cramer, Stephen P

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Phonon-assisted electron-proton transfer in [FeFe] hydrogenases: Topological role of clusters von Chalopin, Yann, Cramer, Stephen P., Arragain, Simon

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Synthesis of the 2Fe subcluster of the [FeFe]-hydrogenase H cluster on the HydF scaffold von Shepard, Eric M, McGlynn, Shawn E, Bueling, Alexandra L, Grady-Smith, Celestine S, George, Simon J, Winslow, Mark A, Cramer, Stephen P, Peters, John W, Broderick, Joan B

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X-ray and Nuclear Spectroscopies to Reveal the Element-Specific Oxidation States and Electronic Spin States for Nanoparticulated Manganese Cyanidoferrates and Analogs von Wang, Hongxin, Huang, Songping D., Young, Anthony T., Cramer, Stephen P., Yoda, Yoshitaka, Li, Lei

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Nuclear resonance vibrational spectroscopy reveals the FeS cluster composition and active site vibrational properties of an O2-tolerant NAD+-reducing [NiFe] hydrogenase von Lauterbach, Lars, Wang, Hongxin, Horch, Marius, Gee, Leland B, Yoda, Yoshitaka, Tanaka, Yoshihito, Zebger, Ingo, Lenz, Oliver, Cramer, Stephen P

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EXAFS and NRVS Reveal a Conformational Distortion of the FeMo-cofactor in the MoFe Nitrogenase Propargyl Alcohol Complex von George, Simon J., Barney, Brett M., Mitra, Devrani, Igarashi, Robert Y., Guo, Yisong, Dean, Dennis R., Cramer, Stephen P., Seefeldt, Lance C.

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Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates von Birrell, James A, Pelmenschikov, Vladimir, Mishra, Nakul, Wang, Hongxin, Yoda, Yoshitaka, Tamasaku, Kenji, Rauchfuss, Thomas B, Cramer, Stephen P, Lubitz, Wolfgang, DeBeer, Serena

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The Electronic Structure of Mn in Oxides, Coordination Complexes, and the Oxygen-Evolving Complex of Photosystem II Studied by Resonant Inelastic X-ray Scattering von Glatzel, Pieter, Bergmann, Uwe, Yano, Junko, Visser, Hendrik, Robblee, John H, Gu, Weiwei, de Groot, Frank M. F, Christou, George, Pecoraro, Vincent L, Cramer, Stephen P, Yachandra, Vittal K

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The large subunit of the regulatory [NiFe]-hydrogenase from Ralstonia eutropha - a minimal hydrogenase? von Caserta, Giorgio, Lorent, Christian, Ciaccafava, Alexandre, Keck, Matthias, Breglia, Raffaella, Greco, Claudio, Limberg, Christian, Hildebrandt, Peter, Cramer, Stephen P., Zebger, Ingo, Lenz, Oliver

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Characterization of a Genuine Iron(V)−Nitrido Species by Nuclear Resonant Vibrational Spectroscopy Coupled to Density Functional Calculations von Petrenko, Taras, DeBeer George, Serena, Aliaga-Alcalde, Núria, Bill, Eckhard, Mienert, Bernd, Xiao, Yuming, Guo, YiSong, Sturhahn, Wolfgang, Cramer, Stephen P, Wieghardt, Karl, Neese, Frank

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