Covalent Intermediates and Enzyme Proficiency von Bruice, Thomas C, Bruice, Paula Yurkanis

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Incorporation of Positively Charged Linkages into DNA and RNA Backbones: A Novel Strategy for Antigene and Antisense Agents von Jain, Moti L, Bruice, Paula Yurkanis, Szabó, István E, Bruice, Thomas C

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Role of the acidity of the ketone in determining the mechanism of enolization via proton abstraction from ketone, carbinolamine, or imine. Catalysis of the enolization of 2,4-penta... von Bruice, Paula Yurkanis

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Formation of a carbinolamine intermediate in the tertiary amine catalyzed enolization of oxaloacetic acid. An alternative mechanism for enolization von Bruice, Paula Yurkanis

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Relative reactivity of amines and oxyanions toward proton abstraction from nitroethane. Electrostatic effects and the reactivity-selectivity principle von Bruice, Paula Yurkanis

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Catalysis of the enolization of oxaloacetic acid by primary and secondary amines via a carbinolamine intermediate von Bruice, Paula Yurkanis

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Diethyl oxaloacetate. Nonconcerted general catalysis of enolization, tertiary amine catalyzed enolization via an addition-elimination mechanism, and general-acid-catalyzed dehydrat... von Bruice, Paula Yurkanis, Bruice, Thomas C

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Solution chemistry of arene oxides von Bruice, Thomas C, Bruice, Paula Y

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Lack of concertedness in the catalysis of the enolization of oxaloacetic acid by general acids and bases. Formation of a carbinolamine intermediate in the tertiary amine catalyzed... von Bruice, Paula Yurkanis, Bruice, Thomas C

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Intramolecular general base catalyzed hydrolysis and tertiary amine nucleophilic attack vs. general base catalyzed hydrolysis of substituted phenyl quinoline-8- and -6-carboxylates von Bruice, Paula Y, Bruice, Thomas C

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Aminolysis of substituted phenyl quinoline-8- and -6-carboxylates with primary and secondary amines. Involvement of proton-slide catalysis von Bruice, Paula Y, Bruice, Thomas C

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Nucleophilic displacement on the arene oxides of phenanthrene von Bruice, Paula Y, Bruice, Thomas C, Yagi, Haruhiko, Jerina, Donald M

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Comparison of the mechanisms of solvolysis and rearrangement of K-region vs. non-K-region arene oxides of phenanthrene. Comparative solvolytic rate constants of K-region and non-K-... von Bruice, Paula Y, Bruice, Thomas C, Dansette, Patrick M, Selander, Hans G, Yagi, Haruhiko, Jerina, Donald M

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Modes of acid catalysis in the aromatization of arene oxides von Bruice, Paula Y, Bruice, Thomas C

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The lack of concertedness in the general acid-base catalysis of the enolization of oxalacetic acid. A case for stepwise nucleophilic-general base catalysis von Bruice, Paula Y, Bruice, Thomas C

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Inactivation of glyceraldehyde-3-phosphate dehydrogenase and yeast alcohol dehydrogenase by arene oxides von Bruice, Paula Yurkanis, Wilson, Susan Crase, Bruice, Thomas C

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Intramolecular catalysis and the involvement of tetrahedral intermediate partitioning in the hydrolysis of benzoylcholine, benzoylthionocholine, and their dimethylamino analogs von Bruice, Paula Yurkanis, Mautner, Henry G

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Multiple pathways for aromatization of 8,9-indan oxide von Kasperek, George J, Bruice, Paula Yurkanis, Bruice, Thomas C, Yagi, Haruhiko, Jerina, Donald M

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Oxygen walk as a complementary observation to the NIH shift von Bruice, Paula Yurkanis, Kasperek, G. J, Bruice, Thomas C, Yagi, H, Jerina, D. M

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